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Thermal switch of oscillation frequency in Belousov-Zhabotinsky liquid marbles

Authors: Adamatzky, Andrew; Fullarton, Claire; Phillips, Neil; Costello, Ben De Lacy;

Thermal switch of oscillation frequency in Belousov-Zhabotinsky liquid marbles

Abstract

A Belousov-Zhabotinsky (BZ) reaction which oscillates globally when mixed and support travelling excitation wave-fronts when not mixed.A liquid marble (LM) is a liquid droplet coated with a hydrophobic powder. We make LMs of 50\ce{\mu}L BZ solution droplets by coating them with a polyethylene powder. We insert a pair of electrodes in BZ LMs and measure an electrical potential difference between the electrodes. Oscillations of electrical potential are observed, with amplitude up to 100~mV and average period of 44~s. We freeze BZ LMs to -1\ce{^0}C and demonstrate that frequency of electrical potential oscillations in a BZ LMs cooled down halves from c.~23~mHz in in intact LM to c.~11~mHz in cooled LM. The frequency returns back to its intact state when the BZ LMs are warm up. Several cycles of frequency halving and doubling can be achieved.

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Keywords

Belousov-Zhabotinsky reaction, oscillations, temperature

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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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