We present WebFAQ, a large-scale collection of open-domain question answering datasets derived from FAQ-style schema.org annotations. In total, the data collection consists of 96 million natural question-answer (QA) pairs across 75 languages, including 47 million (49\%) non-English samples. WebFAQ further serves as the foundation for 20 monolingual retrieval benchmarks with a total size of 11.2 million QA pairs (5.9 million non-English). These datasets are carefully curated through refined filtering and near-duplicate detection, yielding high-quality resources for training and evaluating multilResearch goal: To what extent does training dense retrievers on the bilingual aligned QA pairs in WebFAQ 2.0 improve alignment metrics and retrieval robustness for zero-shot transfer in under-represented languages versus established benchmarks like MKQA?Autonomous synthesis report generated by SOVEREIGN Research Kernel. Tribunal consensus score: 9.3/10.