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ZENODO
Preprint . 2025
License: CC BY
Data sources: ZENODO
ZENODO
Preprint . 2025
License: CC BY
Data sources: Datacite
ZENODO
Preprint . 2025
License: CC BY
Data sources: Datacite
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Exponential Temperature Sensitivity of Ammonia Preservation in Carbonaceous Asteroids

Authors: Smith, Jason; Borabon, Charles;

Exponential Temperature Sensitivity of Ammonia Preservation in Carbonaceous Asteroids

Abstract

This preprint examines the preservation of ammonia in carbonaceous asteroids as a function of peak aqueous alteration temperature. Using published ammonia measurements from returned samples of asteroids (101955) Bennu (OSIRIS-REx) and (162173) Ryugu (Hayabusa2), together with representative CI, CM, and CR carbonaceous meteorites, the study identifies a strong exponential dependence of ammonia abundance on alteration temperature. The analysis shows that relatively modest differences in peak aqueous alteration temperature (on the order of ~40–50 °C) correspond to orders-of-magnitude differences in retained ammonia. This behavior is consistent with Arrhenius-controlled diffusion and desorption kinetics governing the stabilization and release of NH₄⁺ in phyllosilicate matrices. The results indicate that peak alteration temperature, rather than alteration duration or mineralogical extent, is the dominant control on ammonia survival in primitive carbonaceous bodies. By focusing on a minimal, empirically grounded scaling relationship derived entirely from existing measurements, this work resolves an apparent contradiction in the interpretation of volatile inventories among aqueously altered asteroids. The findings provide a predictive framework for volatile preservation, with implications for asteroid targeting, sample-return strategies, and models of reduced nitrogen delivery to the early Earth.Mastodon: @smith_2025

Keywords

volatile preservation, prebiotic chemistry, astrochemistry, nitrogen chemistry, aqueous alteration, Bennu, carbonaceous asteroids, Ryugu, phyllosilicates, ammonia, sample return missions

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average