
This preprint examines the preservation of ammonia in carbonaceous asteroids as a function of peak aqueous alteration temperature. Using published ammonia measurements from returned samples of asteroids (101955) Bennu (OSIRIS-REx) and (162173) Ryugu (Hayabusa2), together with representative CI, CM, and CR carbonaceous meteorites, the study identifies a strong exponential dependence of ammonia abundance on alteration temperature. The analysis shows that relatively modest differences in peak aqueous alteration temperature (on the order of ~40–50 °C) correspond to orders-of-magnitude differences in retained ammonia. This behavior is consistent with Arrhenius-controlled diffusion and desorption kinetics governing the stabilization and release of NH₄⁺ in phyllosilicate matrices. The results indicate that peak alteration temperature, rather than alteration duration or mineralogical extent, is the dominant control on ammonia survival in primitive carbonaceous bodies. By focusing on a minimal, empirically grounded scaling relationship derived entirely from existing measurements, this work resolves an apparent contradiction in the interpretation of volatile inventories among aqueously altered asteroids. The findings provide a predictive framework for volatile preservation, with implications for asteroid targeting, sample-return strategies, and models of reduced nitrogen delivery to the early Earth.Mastodon: @smith_2025
volatile preservation, prebiotic chemistry, astrochemistry, nitrogen chemistry, aqueous alteration, Bennu, carbonaceous asteroids, Ryugu, phyllosilicates, ammonia, sample return missions
volatile preservation, prebiotic chemistry, astrochemistry, nitrogen chemistry, aqueous alteration, Bennu, carbonaceous asteroids, Ryugu, phyllosilicates, ammonia, sample return missions
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