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https://doi.org/10.26434/chemr...
Article . 2025 . Peer-reviewed
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ZENODO
Preprint . 2025
License: CC BY
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ZENODO
Preprint . 2025
License: CC BY
Data sources: Datacite
ZENODO
Preprint . 2025
License: CC BY
Data sources: Datacite
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gGENERIC: A Variational Framework for NonequilibriumThermodynamics via the Entropy Variational Law (EVL)

Authors: Dytrych, Pavel;

gGENERIC: A Variational Framework for NonequilibriumThermodynamics via the Entropy Variational Law (EVL)

Abstract

The GENERIC framework provides a robust structure for nonequilibrium dynamics but lacks a principled method to select reversible (L) and irreversible (M) brackets. Similarly, f inite-time optimizations minimizing path-averaged reciprocal temperature exist but remain isolated. Here, we introduce the Entropy Variational Law (EVL)—a principle elevating minimization of (dS/dE)dE to a guiding rule for nonequilibrium evolution. Embedded in GENERIC, EVL yields gGENERIC, prescribing dynamics via a concrete Poisson–EVL splitting scheme in which the irreversible step is obtained from a local entropy-variational quadratic program. At the continuum level, gGENERIC recovers the standard structure of irreversible thermodynamics and provides a constructive route to bracket selection. Model problems illustrate how gGENERIC reproduces known optimal heating protocols, standard thermodynamic laws, and black-hole-inspired entropy balances, suggesting its usefulness as a flexible building block for entropy-based modelling of nonequilibrium processes in physics and chemistry.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
hybrid