The derived data is part of a manuscript published in the journal ACS Catalysis, entitled "Unveiling the Roles of Pt and CeO2 during Solvent-Free Amide Hydrogenation Utilizing Operando Photoelectron Photoionization Coincidence Spectroscopy". [DOI https://doi.org/10.1021/acscatal.4c07955]. This publication was supported by the EPFL (Switzerland) and NCCR catalysis (grant number 180544 and 225147), a National Centre of Competence in Research funded by the Swiss National Science Foundation (SNSF). A description of the data files (*.xlsx) can be found in the readme.txt The measurements were performed at the Swiss Light Source (Paul Scherrer Institute, CH) and at École Polytechnique Fédérale de Lausanne(EPFL), Lausanne 1015, Switzerland