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Oxidative Transformation of Propan-1-ol Ce (IV) Oxidants (CAN) in Acetonitrile-Water medium, A Kinetic and Mechanistic Study

Name: Oxidative Transformation of Propan-1-ol Ce (IV) Oxidants (CAN) in Acetonitrile-Water medium, A Kinetic and Mechanistic Study
Creator: Bharat Kumar Dhangar
Keywords: propan-1-ol, kinetics, mechanism, oxidation

descriptionPublicationkeyboard_double_arrow_right Journal 01 Nov 2022 English Publisher:International Research Publication House

Authors: Bharat Kumar Dhangar;

doi: 10.5281/zenodo.15067475 , 10.5281/zenodo.15067474

Oxidative Transformation of Propan-1-ol Ce (IV) Oxidants (CAN) in Acetonitrile-Water medium, A Kinetic and Mechanistic Study

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Abstract

Oxidation of Propan-1-ol by Ceric Ammonium Nitrate(CAN) in AcetonitrileWater medium leads to the formation of aldehyde. The reaction is first order with respect to [substrate] concentration in . Michaelies-Menten type of kineticsis observedwith respect to the Propan-1-ol.. The reaction is catalysed by hydrogenions. The hydrogen ion dependence has taking the form kobs =a + b [H+]. The oxidation of Propan-1-ol has been studied in different organic solvents. The solvent effect has been observed by using Kamlet’s and Swain’s multiparametric equations.all experiments were operated at 400 nm.

Related Organizations

Vikram University
India

Keywords

propan-1-ol, kinetics, mechanism, oxidation

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