This dataset contains raw emission data fro three species of Narcissus, recorded using gas chromatography coupled ion mobility spectrometry (Fur further Information of the used technique see: Losch F, Liedtke S, Vautz W, Weigend M (2023) Evaluation of floral volatile patterns in the genus Narcissus using gas chromatography-coupled ion mobility spectrometry. Applications in plant sciences, doi: 10.1002/aps3.11506. The data is stored in excel-worksheets with up to three different tables. For each Sample (2 Individuals of N. viridiflorus, 3 Individuals of N. papyraceus and 3 individuals of N. cantabricus), ~ 150 measurements were conducted over a time period of 72 hours. Table1 consists of an sample identification number, which is composed of the corresponding date-time information. The format of the ID is YY-MM-DD hh:mm. The other columns (P0, P1,P2...) containing the signal intensities (semi-quantitative) of detected compounds for each time stamp. Table2 contains information of the signals, such as the compound name (If signal could be identified), retention time (tR(s)), relative and ion mobility (1/K0).