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Kinetic Modeling Of Transesterification Of Triacetin Using Synthesized Ion Exchange Resin (Siers)

Authors: Hafizuddin W. Yussof; Syamsutajri S. Bahri; Harvey, Adam P.;

Kinetic Modeling Of Transesterification Of Triacetin Using Synthesized Ion Exchange Resin (Siers)

Abstract

{"references": ["Y. Liu, E. Lotero, J. G. Goodwin Jr., & C. Lu. \"Transesterification of triacetin using solid Bronsted bases,\" Journal of Catalysis, 2007, 246, 428-433.", "N. Shibasaki-Kitakawa, H. Honda, H. Kuribayashi, T. Toda, T. Fukumura, & T. Yonemoto. \"Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst,\" Bioresource Technology, 2007, 98, 416-421.", "H. Hattori, M. Shima, & H. Kabashima. \"Alcoholysis of ester and epoxide catalysed by solid bases,\" Studies in surface science and catalysis, 2000, 130 D, 3507-3512.", "Dossin, T.F., Reyniers, M.F. & Marin, G.B. \"Kinetics of heterogeneously MgO-catalyzed transesterification,\" Applied Catalysis B: Environmental, 2006, 62(1-2): 35-45.", "Hayes, R. E. Introduction to Chemical Reactor Analysis. CRC Press, 2001.", "Schwarzer, R.. \"Esterification of acetic acid with methanol: a kinetic study with Amberlyst 15,\" 2006, M. Eng. Thesis, University of Pretoria, South Africa.", "Macleod, C. S. \"Evaluation of heterogeneous catalysts for biodiesel production,\" 2008, PhD Thesis, Newcastle University, UK.", "Eley, D. D. &Rideal, E. K. \"Parahydrogen conversion on Tungsten,\" Nature, 1940, 146, 401-402."]}

Strong anion exchange resins with QN+OH-, have the potential to be developed and employed as heterogeneous catalyst for transesterification, as they are chemically stable to leaching of the functional group. Nine different SIERs (SIER1-9) with QN+OH-were prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene (VBC-DVB) copolymers in the presence of n-heptane (pore-forming agent). The amine group was successfully grafted into the polymeric resin beads through functionalization with trimethylamine. These SIERs are then used as a catalyst for the transesterification of triacetin with methanol. A set of differential equations that represents the Langmuir-Hinshelwood-Hougen- Watson (LHHW) and Eley-Rideal (ER) models for the transesterification reaction were developed. These kinetic models of LHHW and ER were fitted to the experimental data. Overall, the synthesized ion exchange resin-catalyzed reaction were welldescribed by the Eley-Rideal model compared to LHHW models, with sum of square error (SSE) of 0.742 and 0.996, respectively.

Keywords

Anion exchange resin, transesterification., Eley-Rideal, Langmuir-Hinshelwood-Hougen-Watson

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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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