The diffuse Galactic synchrotron emission should exhibit a low level of diffuse circular polarization (CP) due to the circular motions of the emitting relativistic electrons. This probes the Galactic magnetic field in a similar way as the product of total Galactic synchrotron intensity times Faraday depth. We use this to construct an all sky prediction of the so far unexplored Galactic CP from existing measurements. This map can be used to search for this CP signal in low frequency radio data even prior to imaging. If detected as predicted, it would confirm the expectation that relativistic electrons, and not positrons, are responsible for the Galactic radio emission. Furthermore, the strength of real to predicted circular polarization would provide statistical information on magnetic structures along the line-of-sights.