The paper offers a solution to the problem of material flow allocation within a virtual enterprise by using artificial intelligence methods. The research is based on the use of fuzzy relations when planning for optimal transportation modes to deliver components for manufactured products. The Fuzzy Logic Toolbox is used to determine the optimal route for transportation of components for manufactured products. The methods offered have been exemplified in the present research. The authors have built a simulation model for component transportation and delivery for manufactured products using the Simulink graphical environment for building models.