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Article . 1990 . Peer-reviewed
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Magnetic susceptibility of californium fluorides

Authors: Chang, C.-T. P.; Haire, R. G.; Nave, S. E.;

Magnetic susceptibility of californium fluorides

Abstract

Results of magnetic measurements are presented for polycrystalline samples of ${\mathrm{CfF}}_{3}$ (both the hexagonal-${\mathrm{LaF}}_{3}$-type and orthorhombic-${\mathrm{YF}}_{3}$-type crystal structures) and ${\mathrm{CfF}}_{4}$ (monoclinic-${\mathrm{UF}}_{4}$-type). Measurements were performed at temperatures between 4.2 and 340 K and in magnetic fields of up to 50 kG. The effective paramagnetic moments, ${\mathrm{\ensuremath{\mu}}}_{\mathrm{eff}}$, and the Weiss constants, ${\mathit{FTHETA}}_{\mathit{P}}$, have been determined in the Curie-Weiss temperature region (150--340 K). In the trifluorides no significant differences in ${\mathrm{\ensuremath{\mu}}}_{\mathit{e}\mathit{f}\mathit{f}}$ and ${\mathit{FTHETA}}_{\mathit{P}}$ were observed as a function of crystal structure or sample age (radiation damage). For the tetrafluoride, two distinct sets of values for ${\mathrm{\ensuremath{\mu}}}_{\mathit{e}\mathit{f}\mathit{f}}$ and ${\mathit{FTHETA}}_{\mathit{P}}$ were obtained depending on the sample age. Antiferromagnetic ordering was observed in both Cf compounds at temperatures below 12 K. Crystal-field effects were evident in the temperature range between about 12 and 150 K. The calculated susceptibilities for these compounds are presented and discussed.

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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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