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Determination of the Anisotropic Elastic Properties of Rocksalt Ge2Sb2Te5 by XRD, Residual Stress, and DFT

Authors: Cecchini, Raimondo; Kohary, Krisztian; Fernández, Asunción; Cabibbo, Marcello; Marmier, Arnaud;

Determination of the Anisotropic Elastic Properties of Rocksalt Ge2Sb2Te5 by XRD, Residual Stress, and DFT

Abstract

The chalcogenide material GeSbTe is the prototype phase-change material, with widespread applications for optical media and random access memory. However, the full set of its independent elastic properties has not yet been published. In this study, we determine the elastic constants of the rocksalt GeSbTe, experimentally by X-ray diffraction (XRD) and residual stress and computationally by density functional theory (DFT). The stiffnesses (XRD-stress/DFT) in GPa are C = 41/58, C = 7/8, and C = 8/12, and the Zener ratio is 0.46/0.48. These values are important to understand the effect of elastic distortions and nonmelting processes on the performances of increasingly small phase change data bits.

We gratefully acknowledge funding from European FP6 framework program-EXCELL Project NoE 5157032, CSIC (NANO-CONTROL 201060E102), Spanish Ministry MICINN (Consolider FUNCOAT CSD2008-00023), and Junta de Andalucia (TEP217).

Countries
Italy, United Kingdom
Keywords

stress, GeSbTe, thin film, XRD, Ge2Sb2Te5, elastic properties, 530, DFT

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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