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Abstract Fabrication of near-net shaped B 4 C–Co and ZrC–Co composites by slip casting and pressureless sintering is described. It is shown how B 4 C–Co and ZrC–Co concentrated suspensions can be prepared by aqueous colloidal processing, and optimized (in terms of pH, deflocculant contents, and sonication time) to have a shear-thinning rheological behaviour suitable for the near-net shaping of the corresponding cermet compacts by slip casting. It is also demonstrated that the robust, highly-dense compacts so obtained have a uniform green microstructure without macro-defects or gradient density, and which can be fully densified by pressureless sintering. Specifically, it is shown that B 4 C–Co compacts densify by reactive and transient liquid-phase sintering, thus resulting in multi-component ceramics. ZrC–Co compacts densify however by persistent liquid-phase sintering, thus resulting in cermets. An explanation is given for these observations, and general implications are discussed for the near-net shape manufacture of these and similar carbide-metal composites for use in engineering applications.
ZrC, Colloidal processing, Cermets, Pressureless sintering, B4C
ZrC, Colloidal processing, Cermets, Pressureless sintering, B4C
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influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 10% | |
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