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Journal of Alloys and Compounds
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Article . 2019 . Peer-reviewed
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Fine-grained BaTiO3–MgFe2O4 composites prepared by a Pechini-like process

Authors: Roberto Köferstein; Till Walther; Dietrich Hesse; Stefan G. Ebbinghaus;

Fine-grained BaTiO3–MgFe2O4 composites prepared by a Pechini-like process

Abstract

The synthesis of BaTiO3–MgFe2O4 composite powders by a Pechini-like one-pot process and resultingceramic bodies is described herein. Phase formation during the decomposition of homogenous (Ba, Ti,Fe, Mg)-gels was monitored up to 1200 ?C. Composite powders consisting of BaTiO3 and MgFe2O4 wereobtained after decomposition at 700 ?C for 1 h resulting in crystallite sizes of about 10 nm. The shrinkageand sintering behaviour of compacted powders were examined. Sintering at >1200 ?C leads to theformation of hexagonal BaTiO3 only for composites with a MgFe2O4 content of >30 wt.%. SEM imagesof ceramic bodies reveal that the MgFe2O4 particles are surrounded by BaTiO3 crystallites. Magneticmeasurements of both powders and corresponding ceramic bodies show ferrimagnetic behaviour withlow coercivities. At high-field and low temperatures an additional small paramagnetic contributionwas observed which increases with decreasing MgFe2O4 content and should be considered by the calculationof the saturation magnetization.Finally, the

Keywords

sintering, spinel, ceramic, MgFe2O4, nano-particle, Inorganic Chemistry, Chemistry, ferrite, BaTiO3, magnetism, Physical Sciences and Mathematics, Materials Chemistry, ferroelectric, multiferroic, magnetoelectric effect, dielectric, perovskite

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    influence
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
19
Top 10%
Top 10%
Top 10%
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