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Cement and Concrete Research
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Cement and Concrete Research
Article . 2016 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
Cement and Concrete Research
Article . 2016 . Peer-reviewed
http://dx.doi.org/10.1016/j.ce...
Article
License: Elsevier TDM
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Effect of retarders on the early hydration of calcium-sulpho-aluminate (CSA) type cements

Authors: Zajac, Maciej; Skocek, Jan; Bullerjahn, Frank; Ben Haha, Mohsen;

Effect of retarders on the early hydration of calcium-sulpho-aluminate (CSA) type cements

Abstract

Abstract The retardation of calcium-sulpho-aluminate (CSA) type cements by three common retarders—sodium gluconate, sodium–potassium tartrate and borax is investigated at a 2% addition rate. Each of the retarders has a different effect on the early-age hydrate assemblage, as shown by quantitative X-ray diffraction, thermogravimetric analysis, scanning electron microscopy and pore solution analysis. Regardless of the retarder used, the hydration starts with mainly the dissolution of ready soluble (calcium) alkali sulphates and ye'elimite, followed by the formation of ettringite and aluminium hydroxide, whereby the specific clinker mineral dissolution as well as ettringite-forming reaction is delayed in different ways depending on the retarder used. The results showed that the retardation is mainly caused by preventing hydrates formation in the case of tartrate and gluconate. Contrary, borax retards the hydration by preventing to a certain extent the dissolution of ye'elimite and lowers the initial pH. Furthermore, the morphology of ettringite is altered depending on the type of the retarder used.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
186
Top 1%
Top 10%
Top 1%
hybrid