AbstractA series of Fréchet dendronized poly(p‐benzamide)s have been synthesized. To attach the dendron‐functionalities to the poly(p‐benzamide) backbone, a propargyl side chain was introduced to p‐aminobenzoic acid. Then, copper catalyzed azide‐alkyne cycloaddition was used to click a first generation (G1), respectively, a second generation (G2) Fréchet‐dendron azide onto the amino acid monomer. The resulting amino acids were polymerized using triphenylphosphite to obtain a poorly organo‐soluble G1‐dendronized polymer and a non‐aggregating G2‐dendronized polymer showing good organo‐solubility. Furthermore, a strictly alternating non‐aggregating G1‐TEG‐dendronized polymer with good organo‐solubility was synthesized. The aggregation behavior of these polymers was investigated by dynamic light scattering. magnified image