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Acta Crystallographica Section E

Article . 2011

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Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.

Name: Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.
Creator: Xinfang, Wang

descriptionPublicationkeyboard_double_arrow_right Article 14 Jul 2011 English Journal:Acta crystallographica. Section E, Structure reports online, volume 65 (issn: 1600-5368,

Authors: Xinfang, Wang;

pmid: 21578669

pmc: PMC2971939

Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.

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Abstract

In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, which contains a propyl-ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol-ecule in a distorted square-pyramidal geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along the a axis.

Related Organizations

Dezhou University
China (People's Republic of)

10 Research products, page 1 of 1

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{2,2'-[6,6'-Dimethoxy-cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O}cobalt(II) monohydrate.
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Aqua{6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ⁴O,N,N′,O′}(formato-κO)manganese(III) dihydrate
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Monoclinic form of (cyanato-κN){2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ⁴O,N,N′,O′}manganese(III)
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{6,6'-Dimethoxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O}iron(II) monohydrate.
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{4,4′,6,6′-Tetrachloro-2,2′-[(spiro[4.4]nonane-1,6-diyl)bis(nitrilomethylidyne)]diphenolato-κ⁴O,N,N′,O′}nickel(II)
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(Acetone-κO){6,6′-di-tert-butyl-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ⁴O,N,N′,O′}zinc(II)
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The cocrystal aqua-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}-manganese(III)-chlorido{6,6'-di-tert-butyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}(methanol-κO)manganese(III) (1/1).
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