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Cyano(triphenylsilyl)phosphanide as a Building Block for P,C,N Conjugated Molecules

descriptionPublicationkeyboard_double_arrow_right Article 15 Nov 2021 English Publisher:Wiley-VCH
Authors: Le Corre, Grégoire; Gamboa Carballo, Juan José; id_orcid0000-0002-1171-6886; Li, Zhongshu; Grützmacher, Hansjörg; id_orcid0000-0002-1531-8906;

handle: 20.500.11850/515006

Cyano(triphenylsilyl)phosphanide as a Building Block for P,C,N Conjugated Molecules

Abstract

The cyano(triphenylsilyl)phosphanide anion was prepared as a sodium salt from 2-phosphaethynolate. The electronic structure of this new cyano(silyl)phosphanide was studied via computational methods and its reactivity investigated using various electrophiles and Lewis acids, demonstrating its P- and N-nucleophilicity. The ambident reactivity is in agreement with computations. The silyl group also shows lability and therefore the cyano(silyl)phosphanide can be considered as a phosphacyanamide synthon, [PCN]2−, and serves as building block for the transfer of a PCN moiety.

ISSN:1433-7851

ISSN:1521-3773

ISSN:0570-0833

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Keywords

2-phosphaethynolate; anions; cyanophosphines; heterocumulene; phosphorus

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
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Average
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