Structure of a Missing-Caged Metallofullerene: La2@C72

descriptionPublicationkeyboard_double_arrow_right Article 10 Jun 2003 English Publisher:American Chemical Society (ACS)Journal:Journal of the American Chemical Society, volume 125, pages 7,782-7,783 (issn: 0002-7863, eissn: 1520-5126,

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Authors: Haruhito, Kato; Atsushi, Taninaka; Toshiki, Sugai; Hisanori, Shinohara;

doi: 10.1021/ja0353255

pmid: 12822979

Structure of a Missing-Caged Metallofullerene: La2@C72

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Abstract

The La2@C72 metallofullerene having the so-called "missing" C72 fullerene cage was structurally elucidated by using 13C NMR and 139La NMR spectroscopy. The obtained structure of La2@C72 does not satisfy fullerene's structural golden rule, that is, the isolated-pentagon rule. The structure is consistent with a non-IPR D2-C72 (#10611) cage structure where each La atom is situated close to one of the two-fused pentagons.

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Nagoya University
Japan

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