Stereochemical control of reactivity in cobalt(III) alkyl complexes of the tropocoronand ligand system

B. Scott Jaynes; Tong Ren; Axel Masschelein; Stephen J. Lippard

Found an issue? Give us feedback

Journal of the Ameri...arrow_drop_down

Journal of the American Chemical Society

Article . 1993 . Peer-reviewed

Data sources: Crossref

https://dx.doi.org/10.1021/ja0...

Article

Data sources: Microsoft Academic Graph

Stereochemical control of reactivity in cobalt(III) alkyl complexes of the tropocoronand ligand system

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1993 English Publisher:American Chemical Society (ACS)Journal:Journal of the American Chemical Society, volume 115, pages 5,589-5,599 (issn: 0002-7863, eissn: 1520-5126,

Copyright policy )

Authors: B. Scott Jaynes; Tong Ren; Axel Masschelein; Stephen J. Lippard;

doi: 10.1021/ja00066a027

Stereochemical control of reactivity in cobalt(III) alkyl complexes of the tropocoronand ligand system

- Summary
- Related research
  (11)
- Metrics

Abstract

Reduction of the macrocyclic Co II N 4 complexes [Co(TC-3,3)] and [Co(TC-3,4)] with 40% Na/Hg followed by addition of alkyl halide gave the five-coordinate diamagnetic Co(III) alkyl compounds, [CoR(TC-3,3)] (R=Me, Et, n-Pr) and [Co(n-Pr)(TC-3,4)]. Addition of MeLi to a cold THF solution of [CoCl(TC-4,4)] yielded the five-coordinate complex [CoMe(TC-4,4)]. X-ray structural analyses of [CoR(TC-3,3)] (R=Et, n-Pr) and [CoMe(TC-4,4)] revealed that both complexes have square-pyramidal coordination geometries

11 Research products, page 1 of 2

Bioinformatic Analysis of the Genome of the Lactobacillus fermentum 90 TC-4 Production Strain
2019IsAmongTopNSimilarDocuments
ChemInform Abstract: STEREOCHEMICAL AND ELECTRONIC SPIN STATE TUNING OF THE METAL CENTER IN THE NICKEL(II) TROPOCORONANDS
1985IsAmongTopNSimilarDocuments
Substitution of the Lys Linker with the β-Ala Linker Dramatically Decreased the Renal Uptake of ^99mTc-Labeled Arg-X-Asp-Conjugated and X-Ala-Asp-Conjugated α-Melanocyte Stimulating Hormone Peptides
2014IsAmongTopNSimilarDocuments
Variable Nitric Oxide Reactivity of Tropocoronand Cobalt(III) Nitrite Complexes as a Function of the Polymethylene Linker Chain Length
2012IsAmongTopNSimilarDocuments
Heterogeneidad en la metaciclogénesis in vitro de clones derivados de una cepa costarricense de Trypanosoma cruzi (Kinetoplastida: Trypanosomatidae)
2006IsAmongTopNSimilarDocuments
Zinc and Cadmium Tropocoronand Complexes: Effect of Metal Ion Radius on Macrocyclic Ligand Twist and Fold
1997IsAmongTopNSimilarDocuments
Tuning of Electronic Properties and Reactivity in Four-Coordinate Cobalt(III) Complexes by the Tetraazamacrocyclic Tropocoronand Ligand
1997IsAmongTopNSimilarDocuments
Variaciones biológicas de Trypanosoma cruzi (Kinetoplastida:Trypanosomatidae) asociadas con la ingestión de diferentes tipos de sangre por el vector Triatoma dimidiata (Hemiptera: Reduviidae)
2003IsAmongTopNSimilarDocuments
CHARACTERISTICS OF BIOLOGICAL AND MOLECULAR-GENETIC PROPERTIES OF LACTOBACILLUS FERMENTUM 90 TC-4 PROBIOTIC STRAIN
2016IsAmongTopNSimilarDocuments
Stereochemical and electronic spin state tuning of the metal center in the nickel(II) tropocoronands
1985IsAmongTopNSimilarDocuments

chevron_left
1
2
chevron_right

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	29
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Average
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Average