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Portugaliae Electrochimica Acta
Article . 2009 . Peer-reviewed
Data sources: Crossref
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Portugaliae Electrochimica Acta
Article
License: CC BY NC
Data sources: UnpayWall
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Synergistic Effect of Nizoral and Iodide Ions on the Corrosion Inhibition of Mild Steel in Sulphuric Acid Solution

Authors: Obot, Ime B.;

Synergistic Effect of Nizoral and Iodide Ions on the Corrosion Inhibition of Mild Steel in Sulphuric Acid Solution

Abstract

The corrosion rates in the presence of nizoral (NZR), an antifungal drug, as mild steel corrosion inhibitor in 0.1 M H 2SO 4 was measured by the weight loss method in the temperature range from 30 – 50 o C. Results obtained revealed that NZR acts as an inhibitor for mild steel in sulphuric acid solution. Inhibition efficiency increased with increase in concentration of the inhibitor but decreased with increase in temperature. The addition of KI increased the inhibition of NZR to a considerable extent. The experimental results suggest that the presence of iodide ions in the solution stabilized the adsorption of Nizoral molecules on the mild steel surface thereby improving the inhibition efficiency of Nizoral. The adsorption characteristics of the inhibitor were approximated by Langmuir adsorption isotherm and kinetic/thermodynamic adsorption model of El-Awady et al. Mechanism of physical adsorption is proposed from the activation and thermodynamic parameters calculated.

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Keywords

adsorption isotherm, thermodynamics, nizoral, corrosion inhibition, sulphuric acid, mild steel

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
52
Top 10%
Top 10%
Top 10%
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