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Principal components of the cadmium-113 shielding tensors in cadmium sulfate hydrates: a nuclear magnetic resonance study of cadmium coordinated with oxygen

descriptionPublicationkeyboard_double_arrow_right Article 01 Jun 1981 English Publisher:American Chemical Society (ACS)Journal:Journal of the American Chemical Society, volume 103, pages 3,282-3,286 (issn: 0002-7863, eissn: 1520-5126, Copyright policy )
Authors: P. DuBois Murphy; B. C. Gerstein;

doi: 10.1021/ja00402a008

Principal components of the cadmium-113 shielding tensors in cadmium sulfate hydrates: a nuclear magnetic resonance study of cadmium coordinated with oxygen

Abstract

A study is reported of the principal components of the /sup 113/Cd NMR shielding tensors in the salts 3CdSO/sub 4/.8H/sub 2/O and CdSO/sub 4/.H/sub 2/O. A discussion of the sensitivity of the principal components of the /sup 113/Cd shielding tensors to coordination of the cadmium with nearest-neighbor oxygens is presented. An apparent anomaly between the observed shielding anisotropies and the proposed Cd-O bonding distances for 3CdSO/sub 4/.8H/sub 2/O has prompted a refinement of the original crystal structure proposed by Lipson. The refined Cd-O bonding distances are found to be more uniform than those originally reported, in agreement with information inferred from the observed /sup 113/Cd NMR shielding anisotropies.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
32
Average
Top 10%
Top 10%
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