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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Acta Crystallographi...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Acta Crystallographica Section C Crystal Structure Communications
Article . 2006 . Peer-reviewed
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Two isomeric butadiene–N-(acetoxyphenyl)maleimide Diels–Alder adducts: supramolecular structure directed by C—H...X(X= O and π) hydrogen bonds and perpendicular dipole carbonyl–carbonyl interactions

Authors: Jose G, Trujillo-Ferrara; Rosa Luisa, Santillán-Baca; Norberto, Farfán-García; Itzia I, Padilla-Martínez; Efrén V, García-Báez;

Two isomeric butadiene–N-(acetoxyphenyl)maleimide Diels–Alder adducts: supramolecular structure directed by C—H...X(X= O and π) hydrogen bonds and perpendicular dipole carbonyl–carbonyl interactions

Abstract

The molecular and supramolecular structures of 2-(1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-2-yl)phenyl acetate, C16-H15NO4, (I), and its para isomer, 4-(1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-2-yl)phenyl acetate, (II), are reported. The torsion angle between the succinimide and benzene rings depends on the position of the acetoxy substitution [89.7 (1) and 61.9 (1) degrees for (I) and (II), respectively]. The twist of the acetoxy group relative to the mean plane of the benzene ring is almost independent of the acetoxy position [66.0 (1) and 70.0 (1) degrees ]. Packing interactions for both compounds include soft C-H...X (X = O and Ph) interactions, forming chains of centrosymmetric dimers and interlinked chains for (I) and (II), respectively. In addition, three perpendicular dipole C=O...C=O interactions contribute to the supramolecular structure of (II).

Keywords

Maleimides, Magnetic Resonance Spectroscopy, Isomerism, Molecular Structure, Spectrophotometry, Infrared, Butadienes, Hydrogen Bonding, Crystallography, X-Ray

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
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