
pmid: 16518046
The molecular and supramolecular structures of 2-(1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-2-yl)phenyl acetate, C16-H15NO4, (I), and its para isomer, 4-(1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-2-yl)phenyl acetate, (II), are reported. The torsion angle between the succinimide and benzene rings depends on the position of the acetoxy substitution [89.7 (1) and 61.9 (1) degrees for (I) and (II), respectively]. The twist of the acetoxy group relative to the mean plane of the benzene ring is almost independent of the acetoxy position [66.0 (1) and 70.0 (1) degrees ]. Packing interactions for both compounds include soft C-H...X (X = O and Ph) interactions, forming chains of centrosymmetric dimers and interlinked chains for (I) and (II), respectively. In addition, three perpendicular dipole C=O...C=O interactions contribute to the supramolecular structure of (II).
Maleimides, Magnetic Resonance Spectroscopy, Isomerism, Molecular Structure, Spectrophotometry, Infrared, Butadienes, Hydrogen Bonding, Crystallography, X-Ray
Maleimides, Magnetic Resonance Spectroscopy, Isomerism, Molecular Structure, Spectrophotometry, Infrared, Butadienes, Hydrogen Bonding, Crystallography, X-Ray
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