Sparse triangular solve (SpTRSV) is an important linear algebra kernel, finding extensive uses in numerical and scientific computing. The parallel implementation of SpTRSV is a challenging task due to the sequential nature of the steps involved. This makes it, in many cases, one of the most time-consuming operations in an application. Many approaches for efficient SpTRSV on CPU and GPU systems have been proposed in the literature. However, no single implementation or platform (CPU or GPU) gives the fastest solution for all input sparse matrices. In this work, we propose a machine learning-based framework to predict the SpTRSV implementation giving the fastest execution time for a given sparse matrix based on its structural features. The framework is tested with six SpTRSV implementations on a state-of-the-art CPU-GPU machine (Intel Xeon Gold CPU, NVIDIA V100 GPU). Experimental results, with 998 matrices taken from the SuiteSparse Matrix Collection, show the classifier prediction accuracy of 87% for the fastest SpTRSV algorithm for a given input matrix. Predicted SpTRSV implementations achieve average speedups (harmonic mean) in the range of 1.4–2.7\(\times \) against the six SpTRSV implementations used in the evaluation.