
Les solutions aqueuses d’acide β-mercaptopyruvique presentent une tautomerie de pK apparent 9,3: $$ C{H_2}SH - C{(\mathop {OH}\limits_I )_{{2^ - }}}CO{O^ - } + O{H^ - } \rightleftharpoons CH({S^ - }) = C(\mathop {OH}\limits_{II} ) - CO{O^ - } + 2{H_2}O $$
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