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Peroxy acid oxidation : A kinetic and mechanistic study of oxidation of aminobenzoic acids by peroxomonosulfuric acid

Authors: R. S. Panda; Subas Ch. Pradhan;

Peroxy acid oxidation : A kinetic and mechanistic study of oxidation of aminobenzoic acids by peroxomonosulfuric acid

Abstract

Department of Chemistry, Khallikote College (Autonomous), Berhampur-760 001, India Manuscript received 1 march 1999, revised 27 December 1999, accepted 3 March 2000 The kinetics of oxidation of anthranilic acid and p-aminobenzoic acid by peroxomonosulfuric acid have been studied in aqueous medium in the pH range 0-6.4 at 308 K. The reactions are second order - first order each in pcroxy acid and in aminobenzoic acid concentration at constant pH. The reactivity of different peroxo species in the oxidation, has been determined. A mechanism consistent with rate-determining nucleophilic attack of the amino nitrogen on the elcctrophilic peroxo oxygen has been propsed.

Keywords

peroxy acid, oxidation, kinetic

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