Soft template synthesis in the cobalt(III)–1,2-diaminoethane-1,2-dithione–propanone triple system on a K[CoFe(CN)6]-gelatin-immobilized matrix

descriptionPublicationkeyboard_double_arrow_right Article 11 Mar 2008 Russian Federation English Publisher:Springer Science and Business Media LLCJournal:Transition Metal Chemistry, volume 33, pages 523-527 (issn: 0340-4285, eissn: 1572-901X,

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Authors: Mikhailov O.; Kazymova M.;

doi: 10.1007/s11243-008-9075-x

Soft template synthesis in the cobalt(III)–1,2-diaminoethane-1,2-dithione–propanone triple system on a K[CoFe(CN)6]-gelatin-immobilized matrix

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Abstract

Complexation of CoIII, in the form of K[CoFe(CN) 6]-gelatin-immobilized matrix, in contact with aqueous-alkaline solutions (pH ∼ 12) containing 1,2-diaminoethane-1,2-dithione and propanone, has been studied. Template synthesis leading to a chelate CoIII coordination compound with a tetradentate N,N,S,S-donor ligand identified as 4,4,6-trimethyl-1,9-diamino-1,9-dimercapto-3,7-diazanon-3-en-2,8-dithione and hydroxy co-ligand occurs under these specific conditions. 1,2-Diaminoethane-1,2- dithione and propanone are the ligand synthons in this process. © 2008 Springer Science+Business Media B.V.

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Russian Federation

Related Organizations

Kazan State Technological University
Russian Federation
Kazan Federal University
Russian Federation

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