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From Eilatin to Isoeilatin: A Skeletal Rearrangement Strongly Influences π-Stacking of Ru(II) Complex

descriptionPublicationkeyboard_double_arrow_right Article 03 Jun 2004 English Publisher:American Chemical Society (ACS)Journal:Inorganic Chemistry, volume 43, pages 3,792-3,794 (issn: 0020-1669, eissn: 1520-510X, Copyright policy )
Authors: Sheba D, Bergman; Dvora, Reshef; Limor, Frish; Yoram, Cohen; Israel, Goldberg; Moshe, Kol;

doi: 10.1021/ic049806g

pmid: 15206856

From Eilatin to Isoeilatin: A Skeletal Rearrangement Strongly Influences π-Stacking of Ru(II) Complex

Abstract

The C(1)-symmetrical complex [Ru(bpy)(2)(ieil)][PF(6)](2) exhibits unique electrochemical and photophysical properties, and forms discrete dimers in solution and in the solid state held by weak pi-pi stacking interactions via its isoeilatin ligand, preferentially from one of its faces and in a specific orientation.

Related Organizations
Keywords

Alkaloids, Molecular Structure, Organometallic Compounds, Stereoisomerism, Nuclear Magnetic Resonance, Biomolecular, Ruthenium, Phenanthrolines

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
26
Average
Top 10%
Top 10%
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