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The Journal of Chemical Thermodynamics
Article . 2008 . Peer-reviewed
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Article . 2008
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https://dx.doi.org/10.1016/j.j...
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Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 2008 United Kingdom English Publisher:Elsevier BVJournal:The Journal of Chemical Thermodynamics, volume 40, pages 695-701 (issn: 0021-9614, Copyright policy )
Authors: Gardas, Ramesh; Dagade, D.H.; Terdale, S.S.; Coutinho, J.A.P.; Patil, K.J.;

doi: 10.1016/j.jct.2007.10.007

Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K

Abstract

The experimental measurements of the speed of sound and density of aqueous solutions of imidazolium based ionic liquids (IL) in the concentration range of 0.05 mol · kg −1 to 0.5 mol · kg −1 at T = 298.15 K are reported. The data are used to obtain the isentropic compressibility ( β S ) of solutions. The apparent molar volume ( ϕ V ) and compressibility (ϕ K S ) ( ϕ K S ) of ILs are evaluated at different concentrations. The data of limiting partial molar volume and compressibility of IL and their concentration variation are examined to evaluate the effect due to IL–water and IL–IL interactions. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium.

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United Kingdom
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/dk/atira/pure/subjectarea/asjc/1600/1606, 540, name=Physical and Theoretical Chemistry

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
90
Top 10%
Top 10%
Top 10%
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