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{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)samarium(III) methanol disolvate

Name: {μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)samarium(III) methanol disolvate
Creator: Fei Liu
Keywords: Metal-Organic Papers, 01 natural sciences, 3. Good health, 0104 chemical sciences

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 30 Aug 2008Publisher:International Union of Crystallography (IUCr)Journal:Acta Crystallographica Section E Structure Reports Online, volume 65, pages m126-m126 (eissn: 1600-5368,

Authors: Fei Liu;

doi: 10.1107/s1600536808038920 , 10.1107/s1600536808026986 , 10.1107/s1600536808041445

pmid: 21581745 , 21581474 , 21201643

pmc: PMC2968130 , PMC2968012 , PMC2960610

{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)samarium(III) methanol disolvate

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Abstract

In the title dinuclear complex, [NiLa(C19H20N2O4)(NO3)3(CH3OH)2]·2CH3OH, the NiII ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octahedral geometry. The LaIII ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-antiprismatic environment. In the crystal structure, intermolecular O—H—O hydrogen bonds connect complex molecules and methanol solvent molecules, forming a two-dimensional network.

Related Organizations

Eastern Liaoning University
China (People's Republic of)

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Metal-Organic Papers

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14 Research products, page 1 of 2

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