
AbstractDurch Umsatz von K2[VO(SCN)4] mit KNH2 in fl. NH3 wird Vanadylamid VO(NH2)2 erhalten, das schon bei Raumtemperatur NH3 abspaltet und bei 100° in Vanadylimid VO(NH) übergeht. Der thermische Abbau bei 150° liefert Vanadylnitrid (VO)3N2. Vanadylamid hat säureanaloge Eigenschaften, indem es mit KNH2 unter Amidosalzbildung reagiert. Aus dem nicht isolierbaren Amidosalz entsteht durch NH3‐Abspaltung ein Imidonitridosalz K3[(VO)2N(NH)2].
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