Reaction of Sodium Azide with 1,1'–Dicyclohexenyl–Diepoxides

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 2003 English Publisher:Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRJournal:Iranian Journal of Chemistry & Chemical Engineering (issn: 1021-9986,

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Authors: Darvich, Mohammad Raouf; Olyai, Abolfazl; Shabanikia, Akbar; Farkhani, Dariush;

doi: 10.30492/ijcce.2003.8179

Reaction of Sodium Azide with 1,1'–Dicyclohexenyl–Diepoxides

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Abstract

Nucleophilic ring opening of dl and meso 1,1¢- dicyclohexenyl diepoxides by sodium azide in dioxane and aqueous alcoholic medium give the corresponding azidoalcohols. The obtention of departure diepoxides from diazidoalcohols by the reaction with sodium hydride shows the anti position of OH and N3 groups.

Related Organizations

University of Tehran
Iran (Islamic Republic of)
Research Institute of Petroleum Industry
Iran (Islamic Republic of)

Keywords

Chemistry, Chemical engineering, 1,1' – dicyclohexenyl – diepoxides, nucleophilic opening, sodium azide, TP155-156, trans diaxial, QD1-999, azido-alcohols

3 Research products, page 1 of 1

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