Fluordiazadiphosphetidine, 14. Mitt.: Nucleophile Substitutionsreaktionen von 1-Chlormethyl-2,2,2,4,4,4-hexafluor-3-methyl-1,3,2?5,4?5-diazadiphosphetidin und 1,3-Bis(chlormethyl)-2,2,2,4,4,4-hexafluor-1,3,2?5,4?5-diazadiphosphetidin mit ausgew�hlten metallorganischen Reagentien

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 1985 German Publisher:Springer Science and Business Media LLCJournal:Monatshefte f�r Chemie Chemical Monthly, volume 116, pages 157-166 (issn: 0026-9247, eissn: 1434-4475,

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Authors: Heinrich Hahn; Wolfgang Meindl; Kurt Utvary;

doi: 10.1007/bf00798451

Fluordiazadiphosphetidine, 14. Mitt.: Nucleophile Substitutionsreaktionen von 1-Chlormethyl-2,2,2,4,4,4-hexafluor-3-methyl-1,3,2?5,4?5-diazadiphosphetidin und 1,3-Bis(chlormethyl)-2,2,2,4,4,4-hexafluor-1,3,2?5,4?5-diazadiphosphetidin mit ausgew�hlten metallorganischen Reagentien

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Abstract

Photochemical chlorination of (CH3NPF3)2 yields ClCH2(NPF3)2CH3(I) and ClCH2(NPF3)2CH2Cl (II). By reaction with organometallics unsymmetric N-substituted hexafluorodiazadiphosphetidines are synthesized. Depending on the nucleophilic strength of the used organometallic the chlorine atom of the N-CH2Cl group can be selectively substituted versus an organic substituent without side-reaction at the phosphorus atom.

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Fluordiazadiphosphetidine. 8. Mitt. Die photochemische chlorierung von 2,2,2,4,4,4-Hexafluoro-1,3-dimethyl-1,3,2?5,4?5-diazadiphosphetidin
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