Incorporation of nitrate ions into halobismuthates

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 2020 English Publisher:Elsevier BVJournal:Inorganica Chimica Acta, volume 511, page 119,754 (issn: 0020-1693,

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Authors: Souvik Pandey; Prajisha Pradeep; Anjali Venugopal M; A.A. Aswanth; Alex P. Andrews; Ajay Venugopal;

doi: 10.1016/j.ica.2020.119754

Incorporation of nitrate ions into halobismuthates

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Abstract

Abstract Two binuclear halobismuthates (Bi2X10)4− (X = Cl (1) and Br (2)) containing m-phenylenediammonium cation [mPDA-(H)2]2+ or [mPDA-(H)]1+ starting from corresponding BiX3 (X = Cl, Br) and their nitrate derivatives i.e., [Bi2X8(NO3)2][mPDA-(H)2]2 (X = Cl (3) and Br (4)) starting from Bi(NO3)3,5H2O have been synthesized. 3 and 4 are the first examples of mixed halobismuthates where nitrate ions are coordinated to bismuth centers along with other halide ions. All the compounds have been characterized by single crystal XRD, elemental analysis and IR spectroscopy. The structural comparisons of 1–4 have been discussed.

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