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A Comparative Cation Exchange Study of the Lanthanide Atrolactate and α‐Hydroxyisobutyrate Complexes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1972 English Publisher:WileyJournal:Bulletin des Sociétés Chimiques Belges, volume 81, pages 369-378 (issn: 0037-9646, eissn: 0037-9646,

Authors: F. Verbeek; H. Thun;

doi: 10.1002/bscb.19720810135

A Comparative Cation Exchange Study of the Lanthanide Atrolactate and α‐Hydroxyisobutyrate Complexes

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Abstract

AbstractIn order to compare α‐hydroxyisobutyrate and atrolactate as complexing eluants for the separation of lanthanide ions on cation exchange resins, the distribution constants for a number of their lanthanide complexes were determined simultaneously at 25±0.1 ° and ionic strength 0.2 with ammonium perchlorate in aqueous solution. Column techniques were used to compare the HETP of the Tb‐complex with each ligand. Finally a comparative test separation was carried out on a mixture of lanthanide ions. In view of the results atrolactate should not be considered as a promising alternative for α‐hydroxyisobutyrate as it offers only little improvement.

12 Research products, page 1 of 2

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