Syntheses and structures of an unsolvated tetrakisimidophosphate {Li3[P(NBut)3(NSiMe3)]}2 and the face-sharing double-cubane {Li2(THF)[P(O)(NBut)2(NHBut)]}2

descriptionPublicationkeyboard_double_arrow_right Article 13 Sep 2002Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications (issn: 1359-7345, eissn: 1364-548X,

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Authors: Andrea, Armstrong; Tristram, Chivers; Mark, Krahn; Masood, Parvez; Gabriele, Schatte;

doi: 10.1039/b207197e

pmid: 12448411

Syntheses and structures of an unsolvated tetrakisimidophosphate {Li3[P(NBut)3(NSiMe3)]}2 and the face-sharing double-cubane {Li2(THF)[P(O)(NBut)2(NHBut)]}2

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Abstract

The treatment of Me3SiN=P(NHBut)3 with three equivalents of LiBun in toluene produces (Li3(P(NBut)3(NSiMe3)))2 comprised of a Li6N6 cyclic ladder capped on the two hexagonal faces by mu 3-PNSiMe3 groups; the corresponding reaction of O=P(NHBut)3 yields the face-sharing double-cubane (Li2(THF)P(O)(NBut)2(NHBut))2 with a central Li2O2 ring.

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