The thermal and hydrolytic inter-relationship between the products of the antimony(III) chloride/water system

descriptionPublicationkeyboard_double_arrow_right Article 01 Apr 1985 English Publisher:Elsevier BVJournal:Thermochimica Acta, volume 85, pages 31-34 (issn: 0040-6031,

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Authors: J. Fenerty; J. Pearce; S.A. Jones;

doi: 10.1016/0040-6031(85)85522-2

The thermal and hydrolytic inter-relationship between the products of the antimony(III) chloride/water system

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Abstract

Abstract Controlled hydrolysis of SbCl 3 resulted in two well defined intermediate oxychlorides; SbOCl and Sb 4 O 5 Cl 2 . TG indicated that SbOCl decomposed rapidly at 530K to Sb 4 O 5 Cl 2 . Chemical analysis and XRD showed that the decomposition product was identical to Sb 4 O 5 Cl 2 produced by the hydrolysis of SbCl 3 . Complete hydrolysis of SbCl 3 and the thermal decomposition of intermediate oxychlorides both gave Sb 2 O 3 ; the product of hydrolysis was shown by XRD to be valentite, whilst that obtained by thermal decomposition was senarmontite. Our findings have been related to the synergistic effect of Sb 2 O 3 , a flame retardant additive, in conjunction with chlorinated hydrocarbons.

8 Research products, page 1 of 1

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