<script type="text/javascript">
<!--
document.write('<div id="oa_widget"></div>');
document.write('<script type="text/javascript" src="https://www.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=undefined&type=result"></script>');
-->
</script>

COPY SCRIPT

For further information contact us at helpdesk@openaire.eu

Kinetics of Oxidation of Atrolactic Acid by V (v)

Name: Kinetics of Oxidation of Atrolactic Acid by V (v)
Keywords: Synthesis, solution, sodium

descriptionPublicationkeyboard_double_arrow_right Article 31 May 1969 English Publisher:Zenodo

Authors: J. N. Kar; G. B. Behera; M. K. Rout;

doi: 10.5281/zenodo.6460666 , 10.5281/zenodo.6460667

Kinetics of Oxidation of Atrolactic Acid by V (v)

- Summary
- Subjects
- Related research
  (10)
- Metrics

Abstract

The kinetics of oxidation of Atrolactic acid with V(v) has been studied. The oxidation was found to be of fiNt order with respect to V(v) and to Atrolactic acid.The activation energy, frequency factor and entropy of activation were found to be 15·56 K.Cals, 5·9x 107 Sec.-1 and 20·18 E.U. The oxidation was found to be acid dependent, the rate increasing with increasing concentration of the acid. This acid dependence was found to be related to o [H3O+] but not to Hammett's\(h\)\(o\) . Addition of some metal sulphates did not indicate any primary salt effect. Tho oxidation appeared to proceed through an mitial complex formation and subsequently through free radicals. The equilibrium constant for the formation of complex and its rate of decomposition have been calculated.

Related Organizations

Keywords

Synthesis, solution, sodium

10 Research products, page 1 of 1

An Investigation of the Inherent Chiral Induction Ability of Axially Chiral 1,1′-Binaphthalene Framework in the Prelog’s Atrolactic Acid Synthesis
1992IsAmongTopNSimilarDocuments
Kinetics of Oxidation of Atrolactic Acid by Ceric Salt
1970IsAmongTopNSimilarDocuments
High performance liquid chromatographic enantioseparation of atrolactic acids using chiral mobile phase additive
2014IsAmongTopNSimilarDocuments
A Comparative Cation Exchange Study of the Lanthanide Atrolactate and α‐Hydroxyisobutyrate Complexes
1972IsAmongTopNSimilarDocuments
Effect of pressure on the asymmetrical synthesis of atrolactic acid
1972IsAmongTopNSimilarDocuments
Stereoselective action of acylated crude papain toward mandelic and atrolactic hydrazides
1982IsAmongTopNSimilarDocuments
The Cerium–Zirconium Binary Oxide as an Efficient Catalyst for Oxidation of α-Methylstyrene Oxide into Atrolactic Acid
2020IsAmongTopNSimilarDocuments
Asymmetric Synthesis with Sugar Derivatives. III. Action of Methylmagnesium Iodide on Sugar Esters of Phenylglyoxylic Acid
1967IsAmongTopNSimilarDocuments
The Configuration of Atrolactic Acid. Retention of Configuration in the Acid-catalyzed Ring Opening of Stilbene Oxides¹
1956IsAmongTopNSimilarDocuments
The stability of some lanthanide complexes with mandelate and atrolactate
1966IsAmongTopNSimilarDocuments

Impact byBIP!

	citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	0
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Average
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Average
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Average

Usage byUsageCounts

visibility	views	5
download	downloads	5

5
views
5
downloads
Powered by

Found an issue? Give us feedback

visibility

download

Average

Green