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Gas-Phase Fragmentation of Cyclic Oligosaccharides in Tandem Mass Spectrometry

Authors: Alexander O. Chizhov; Yury E. Tsvetkov; Nikolay E. Nifantiev;

Gas-Phase Fragmentation of Cyclic Oligosaccharides in Tandem Mass Spectrometry

Abstract

Modern mass spectrometry, including electrospray and MALDI, is applied for analysis and structure elucidation of carbohydrates. Cyclic oligosaccharides isolated from different sources (bacteria and plants) have been known for decades and some of them (cyclodextrins and their derivatives) are widely used in drug design, as food additives, in the construction of nanomaterials, etc. The peculiarities of the first- and second-order mass spectra of cyclic oligosaccharides (natural, synthetic and their derivatives and modifications: cyclodextrins, cycloglucans, cyclofructans, cyclooligoglucosamines, etc.) are discussed in this minireview.

Keywords

Spectrometry, Mass, Electrospray Ionization, electrospray ionization, laser-induced desorption/ionization, Organic chemistry, Oligosaccharides, Review, cyclooligoglucosamines, QD241-441, Tandem Mass Spectrometry, fragmentation, tandem mass spectrometry, cyclosophoraoses, cyclofructans, cyclodextrins, Molecular Structure, cyclolaminarinoses, structure elucidation, cyclooligosaccharides, matrix-assisted, macrocycles, collision induced dissociation, Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization, cycloglycans

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
17
Top 10%
Average
Top 10%
Green
gold
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