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Preparation and preliminiar evaluation of new organometallic bases from cis-2,6-dimethylpiperidine

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Dec 2013Publisher:Editora Edgard BlücherJournal:Proceedings of the 15th Brazilian Meeting on Organic Synthesis Proceedings
Authors: Giuliano C. Clososki; Evelyn Mirella Lopes Pina; Natália de Araujo Pereira; Rafael A. Soldi;

doi: 10.5151/chempro-15bmos-bmos2013_2013915232924

Preparation and preliminiar evaluation of new organometallic bases from cis-2,6-dimethylpiperidine

Abstract

Recently, magnesiate and zincate reagents have proven their synthetic importance for the functionalization of arenes. 1 In addition, mixed Li/Mg and Li/Zn amides prepared from 2,2,6,6tetramethylpyperidine (TMPH) are highly soluble and active bases that allow smoothly metalatation of various aromatic and heteroarenes with an excellent fuctional group tolerance. 2 In this work, we have been investigating the preparation and the reactivity of mixed metal bases from cis-2,6-dimethylpiperidine (DMPH) as alternative for TMP-metal bases.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
bronze
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