Carboxymethyl-selenopyruvic acid as the product of the oxidative deamination of carboxymethyl-selenocysteine.
Copyright policy )Carboxymethyl-selenopyruvic acid as the product of the oxidative deamination of carboxymethyl-selenocysteine.
CMSeC labeled with 14C in the carboxymethyl moiety was incubated with snake venom L-aminoacid oxidase. As the product of the reaction only one ketoacid was detected, which retained all the radioactivity of the oxidized substrate. This clearly shows that no breakdown of the C-Se bond of CMSeC occurs during its oxidation, and confirms previously reported data indicating that the ketoacid arising from CMSeC is CMSeP.
Selenium, Deamination, Carbocysteine, Amino Acid Oxidoreductases, Cysteine, Pyruvates, amino acid oxidoreductases; analogs /&/ derivatives; analogs /&/ derivatives/metabolism; carbocysteine; cysteine; deamination; isolation /&/ purification/metabolism; metabolism; oxidation-reduction; pyruvates; selenium, Oxidation-Reduction
Selenium, Deamination, Carbocysteine, Amino Acid Oxidoreductases, Cysteine, Pyruvates, amino acid oxidoreductases; analogs /&/ derivatives; analogs /&/ derivatives/metabolism; carbocysteine; cysteine; deamination; isolation /&/ purification/metabolism; metabolism; oxidation-reduction; pyruvates; selenium, Oxidation-Reduction
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