The membrane enrichment process of traditional Chinese medicine volatile oil is environmental friendly and practical, with a good application prospect. In this article, oil-bearing solutions of eight traditional Chinese medicines, namely Caryophylli Flos, Schizonepetae Herba, Eupatorii Herb, Acori Talarinowii Rhizoma, Magnoliae Flos, Chrysanthemum indicum, Cyperi Rhizoma and Citri Reticulatae Pericarpium Viride, were taken as the experimental system. Under unified conditions (membrane: PVDF-14W, temperature: 40 degreeC, pressure: 0. 1 MPa, membrane surface speed: 150 r min- 1), trans-membrane was conducted for above eight oil-bearing solutions to explore the effect of their oil-bearing solution environment on system flux and oil recovery rate. The results showed that systems with smaller pH had a lower flux, without significant effect on oil recovery rate. Greater differences between the surface tension of solutions and that of pure water contributed to a lower oil recovery rate. The conductivity had no notable effect on membrane enrichment process. Systems with high turbidity had a lower flux, without remarkable effect on oil recovery rat. Heavy oils showed lower flux than light ones, but with a slightly higher oil recovery rat. Systems with higher viscosity had a lower flux than those with lower viscosity. Except for Magnoliae Flos volatile oil, all of the remaining volatile oils showed a much higher oil recovery rat than systems with high viscosity. The above results could provide data support and theoretical basis for the industrialization of membrane enrichment volatile oil technology.