Longquan celadon not only has been loved widely by the domestic and international ceramic lovers, but also imitated by the kiln workers from different places. Among all of the imitated celadons, the most representative products appeared in Ming and Qing dynasties. This paper used EDXRF to test 38 pieces of Longquan celadon of Song, Yuan and Ming dynasty and imitated Longquan celadon in Jingdezhen of Ming dynasty, combined with firing temperature in order to analyze the different composition characteristics of the bodies and the glaze, evolution rule and formation reasons of these samples in the two different places from the views of time and space. It will be contributed to realising the evolution development, mutual communication and influence of the southern celadon and also provide a scientific basis to get the exact information of the celadon including its time and place of origin and so on.