Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle.
Copyright policy )Ca(BH4)2-Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle.
The Ca(BH4)2-Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed.
- University of Pavia Italy
- University of Turin Italy
- National Institute for Nuclear Physics Italy
DECOMPOSITION, SORPTION PROPERTIES, HYDRIDE COMPOSITES, 500, MG2NIH4, Ca borohydride, Chemistry (all); Catalysis; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Surfaces, Coatings and Films; Materials Chemistry2506 Metals and Alloys; 2506, 540, BOROHYDRIDES, hydrogen storage, ddc: ddc:620.11
DECOMPOSITION, SORPTION PROPERTIES, HYDRIDE COMPOSITES, 500, MG2NIH4, Ca borohydride, Chemistry (all); Catalysis; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Surfaces, Coatings and Films; Materials Chemistry2506 Metals and Alloys; 2506, 540, BOROHYDRIDES, hydrogen storage, ddc: ddc:620.11
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