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Fractura y mecanismos de deformación de un polipropileno reforzado con cenizas y modificado con un copolímero de bloque

Authors: García Pardo, Santiago;

Fractura y mecanismos de deformación de un polipropileno reforzado con cenizas y modificado con un copolímero de bloque

Abstract

[Resumen] En esta memoria se presenta los resultados del estudio de la fractura y los mecanismos de deformación de materiales compuestos basados en polipropileno (PP), un copolímero olefínico de bloque (OBC) y cenizas provenientes de la combustión de biomasa forestal modificadas con un agente de acoplamiento tipo silano y procesados mediante técnicas de extrusión. Se han caracterizado las propiedades mecánicas de los nuevos materiales estudiados mediante el análisis de su resistencia a tracción, impacto y dureza, relacionándolos con su morfología, observada por microscopía electrónica de barrido (SEM). Las propiedades térmicas de los materiales compuestos y la matriz polimérica, han sido analizadas mediante análisis por calorimetría diferencial de barrido (DSC), análisis termogravimétrico (TGA) y la temperatura de flexión bajo carga (HDT). Se evaluaron los parámetros de fractura en condiciones de baja y moderada alta velocidad, así como, los mecanismos de deformación que intervienen durante el proceso de fractura para cada formulación de los nuevos materiales.

[Resumo] Nesta memoria, preséntase os resultados do estudio da fractura e deformación de compostos de polipropileno (PP), un copolímero olefínico en bloque (OBC) e cinzas, procedentes da queima de biomasa forestal, modificadas cun axente de acoplamento silano e procesadas por técnicas de extrusión. Caracterizáronse as propiedades mecánicas dos novos materiais mediante a súa resistencia á tracción, ó impacto e a morfoloxía asociada obtida por microscopia electrónica de varrido (SEM). As propiedades térmicas dos novos materiais compostos e a matriz polimérica, foron estudados por calorímetría diferencial de varrido (DSC), análise termogravimétrico (TGA) e a súa temperatura de flexión baixo carga (HDT). Foron avaliados os parámetros de fractura en baixa e moderada velocidade. Determinaronse tamén os mecanismos de deformación implicados no proceso de fractura de cada formulación dos novos materiais compostos.

[Abstract] In this work, the fracture and failure behaviour of environmentally friendly composites based on polypropylene (PP), an olefin block copolymer (OBC) and ash, from wood combustion, modified with a silane coupling agent were investigated. The mechanical properties of new composites have been characterized by analyzing their tensile properties, impact toughness and associated morphology by scanning electron microscopy (SEM). The thermal properties of the new materials and the polymer matrix were analized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and measuring their heat deflection temperature (HDT). The fracture parameters were determined at low and moderately high speed. The role of deformation mechanisms, involved during the process of fracture, was investigated by SEM and optical microscopy.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
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