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Enzymatically treated sulphite pulp to give dissolving-pulp characteristics

Authors: Quintana, Elisabet; Valls Vidal, Cristina; Vidal Lluciá, Teresa; Roncero Vivero, María Blanca;

Enzymatically treated sulphite pulp to give dissolving-pulp characteristics

Abstract

Bleached cellulose with good end-properties (~90% ISO brightness, < 0.5 kappa number and substantially preserved cellulose integrity) was obtained by using a totally chlorine-free (TCF) biobleaching sequence. The initial pulp was subjected to an overall LQPo sequence. Unbleached sulphite cellulose was treated with Trametes villosa laccase (L) in combination with violuric acid (VA). This enzymatic stage was followed by a chelating stage (Q) and then by a hydrogen peroxide stage reinforced with pressurized oxygen (Po). The use of violuric acid was dictated by the results of a preliminary study, where the bleaching efficiency of various natural (syringaldehyde and pcoumaric acid) and synthetic mediators (violuric acid and 1-hydroxybenzotriazole) were assessed. The outstanding results obtained with laccase-violuric acid system fulfil the characteristics of commercial dissolving-grade pulp with the added advantage that the enzymatic treatment saved 2h of reaction time and about 70% of hydrogen peroxide consumption, relative to a conventional hydrogen peroxide sequence (Po)

Country
Spain
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Keywords

Wood-pulp--Bleaching, Àrees temàtiques de la UPC::Enginyeria paperera::Pasta paperera::Blanqueig de pastes, Polpa de fusta -- Blanqueig, Biobleaching, Violuric acid, Àrees temàtiques de la UPC::Enginyeria paperera::Primeres matèries papereres::Cel·lulosa, :Enginyeria paperera::Pasta paperera::Blanqueig de pastes [Àrees temàtiques de la UPC], :Enginyeria paperera::Primeres matèries papereres::Cel·lulosa [Àrees temàtiques de la UPC], Cel·lulosa per a paper, Sulphite pulp, Cellulose, Wood--Chemistry, Dissolving pulp

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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