Based on the long-term located observation of forest ecosystem, and by using the 2006 forest resources inventory data of Liaoning Province and the forest industry standard of the People's Republic of China( LY/T 1721-2008, specification for assessment of forest ecosystem services in China), an evaluation was made on the material quantity and services value of main forest ecosystems in fourteen cities of Liaoning Province. In this province, the forest ecosystem services value supplied by water storage, soil conservation, C fixation, O2 release, nutrients accumulation, environment purification, biodiversity conservation, and forest recreation in 2006 was 2591.72 x 10(8) yuan, which was 8.54 times of the forestry production value and 28.02% in the GDP of the province. The services value of water storage, biodiversity conservation, C fixation, and O2 release occupied 79.09% of the total, being the main forest ecosystem services in the province. Economic forest and shrub had smaller per unit services value but larger area, and hence, their ecosystem services value should not be ignored. Abies fargesii forest, Phellodendron amurense forest, Juglans mandshurica forest, and Fraxinus mandshurica forest were the representative zonal vegetations in Liaoning Province, which had high value in biodiversity conservation. Under the effects of climate and other factors, the forest area and forest quality in west Liaoning were lower than those in east Liaoning.