A one-dimensional polyoxometalate-based polymer [Cu(DMF)₆][PMo(V)Mo(VI)₁₁O₄₀Cu(DMF)₄]·DMF: crystal structure and luminescent properties.
Copyright policy )A one-dimensional polyoxometalate-based polymer [Cu(DMF)₆][PMo(V)Mo(VI)₁₁O₄₀Cu(DMF)₄]·DMF: crystal structure and luminescent properties.
The polyoxometalate-based 1D coordination polymer [[Cu(DMF)₆][PMo(V)Mo(VI)₁₁O₄₀Cu(DMF)₄]·DMF1 was synthesized and characterized by IR, UV spectroscopy and single-crystal X-ray diffraction analysis. Each Cu(II) center has a distorted octahedral coordination geometry. Cu(1) center interconnects with two [PMo(V)Mo(VI)₁₁O₄₀]⁴⁻ anion subunits and each [PMo(V)Mo(VI)(11)O(40)]⁴⁻ polyoxoanion acts as a didentate ligand to link two Cu centers through two terminal oxygen atoms to form a one-dimensional chain structure. The luminescent properties of 1 in the solution and in the solid state were investigated, respectively.
- Henan University China (People's Republic of)
Luminescence, Molecular Structure, Polymers, Polyoxometalates, Tungsten Compounds, Crystallography, X-Ray
Luminescence, Molecular Structure, Polymers, Polyoxometalates, Tungsten Compounds, Crystallography, X-Ray
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