Synthesis and structure of [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf, containing a [MeAl(mu-PMes)(PMes)]2(4-) tetraanion (Mes = 2,4,6-Me3C6H2).

Felipe, García; Robert, Haigh; Mary, McPartlin; Dominic S, Wright

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Chemical Communicati...arrow_drop_down

Chemical Communications

Article . 2004

Data sources: Europe PubMed Central

Synthesis and structure of [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf, containing a [MeAl(mu-PMes)(PMes)]2(4-) tetraanion (Mes = 2,4,6-Me3C6H2).

descriptionPublicationkeyboard_double_arrow_right Article 26 Jan 2004 English Journal:Chemical communications (Cambridge, England) (issn: 1359-7345,

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Authors: Felipe, García; Robert, Haigh; Mary, McPartlin; Dominic S, Wright;

pmid: 12934907

Synthesis and structure of [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf, containing a [MeAl(mu-PMes)(PMes)]2(4-) tetraanion (Mes = 2,4,6-Me3C6H2).

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Abstract

The reaction of MeAlCl2 with MesPHLi (1:4 equivalents) in thf/toluene gives the cage complex [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf (1), containing an [[MeAl(mu-PMes)(PMes))2]4- tetraanion which is valence-isoelectronic with extensively studied Group 15 anions of the type [E(mu-NR)(NR)]2(2-).

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University of Cambridge
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