In this paper we present visible and near-infrared spectroscopy of 7 peculiar NEOs. These objects have been observed within the SINEO (Spectral Investigation of Near-Earth Objects) survey, which have produced more then 100 spectra of NEOs. Among the objects presented here, five of them result to be spectrally peculiar, belonging to the rare V and R classes. The other two have peculiar orbits being comet-like. Their spectroscopy gives a B- and a X-type which is compatible with the scenario of being objects which originated in the outer Solar System.